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The Core Distinction
Proof of Work: Miners compete to solve a computational puzzle. The winner adds the next block and earns a reward. Security comes from the physical cost of computation (energy, hardware). Attacking a PoW network requires controlling 51% of the total hashrate — enormously expensive.
Proof of Stake: Validators are chosen to add blocks in proportion to the ETH they have "staked" (locked as collateral). Security comes from the economic cost of holding stake. Attacking a PoS network requires controlling 33% of staked ETH ($20B+ today) — and the attacker's stake can be slashed if they misbehave.
What This Means for Building
Energy: PoS is 99.95% more energy-efficient than PoW. Ethereum's Merge (September 2022) reduced its energy consumption from ~70 TWh/year to ~0.01 TWh/year. For corporate sustainability requirements: PoS blockchains (Ethereum, Polygon, Solana) are the appropriate choice.
Security model: PoW's security scales with the cost of energy and hardware — physical and hard to amass suddenly. PoS's security scales with the financial cost of staked assets — potentially faster to attack if ETH price dropped dramatically. Both are considered production-secure at current scale.
Finality: PoW has probabilistic finality (60 confirmations = ~1 hour for strong confidence on Bitcoin). PoS has economic finality after ~12.8 minutes on Ethereum — faster and more absolute.